Titanium Anodes

Hele Titanium, a leading manufacturer of titanium anodes, specializes in high-quality MMO Anodes. With a decade of expertise, we offer customized solutions featuring Ruthenium, Iridium, and Platinized coatings, ensuring both quality and affordability. Trust in Hele Titanium for unparalleled manufacturing excellence, meticulously tailored to meet your needs.

Elevate Your Industrial Efficiency with Premium Titanium Anodes

Titanium Anodes are crucial for sectors that prioritize durability and efficiency, such as water treatment and electroplating. Hele Titanium’s anodes stand out for their corrosion resistance and long-lasting performance, ensuring your operations are both reliable and cost-effective. Customizable to specific needs, these anodes optimize functionality and extend the lifespan of your systems.

Choosing Hele Titanium means investing in superior longevity and efficiency. Our anodes are designed for easy integration and low maintenance, meeting rigorous industry standards. Enhance your operations with Hele Titanium’s Titanium Anodes, your key to advanced performance and sustainable results. Propel your industrial capabilities forward with Hele Titanium’s tailored anode solutions.

Ru+Ir Coated Titanium Electrode

Ru+Ir Coated Titanium Electrode

Elevate your electrochemical processes with our Ruthenium Iridium Titanium Anode. Tailored for you, it promises unmatched durability, superior conductivity, and exceptional corrosion resistance — all in one innovative solution.

Iridium Ta-Coated Titanium Electrode

Iridium Ta-Coated Titanium Electrode

Elevate your operations with our Iridium Ta-Coated Titanium Electrode. Tailored for your demanding applications, it guarantees exceptional conductivity and unmatched corrosion resistance — ensuring you achieve consistently reliable results.

Platinized Electrode

Platinized Titanium Anodes

Elevate your electrochemical processes with our Platinized Titanium Anodes. Designed with a premium platinum coating tailored for your sophisticated applications, they promise unparalleled efficiency and superior corrosion resistance — ensuring you achieve optimal performance every time.

PEM Electrolyzer

PEM Electrolyzer

Transform your hydrogen production with our state-of-the-art PEM Electrolyzer. Built with a resilient titanium anode, it’s tailored to offer you unparalleled efficiency and reliability. Beyond performance, it stands as a testament to your commitment to sustainable technology and forward-thinking operations.

Cathodic Protection Anode

Cathodic Protection Anode

Guard your valuable assets with our elite ICCP Anodes and sacrificial anodes, meticulously crafted for cathodic protection. Designed to extend the lifespan of your infrastructure by expertly deflecting corrosion, they offer you peace of mind and assurance of enduring quality. Choose unparalleled protection; choose Hele Titanium

Water Treatment Anode

Water Treatment Anode

Elevate your water purification processes with our specialized titanium anodes. Crafted meticulously for water treatment, they excel in contaminant removal while providing superior corrosion resistance. Ensure cleaner, safer water for your operations, reaffirming your commitment to excellence and health.

Electrowinning Electrode

Electroplating Anode

Achieve impeccable metal finishes with our superior titanium anodes, meticulously crafted for electroplating endeavors. Tailored to offer unmatched conductivity and corrosion resistance, they empower your operations, ensuring precision and excellence at every step. Partner with us, and set a new benchmark in electroplating quality.

Electrowinning Electrode

Electrowinning Electrode

Unlock unparalleled metal recovery with our precision-engineered titanium anodes tailored for electrowinning electrodes. If dependable results and optimized metal extraction are what you seek, trust in Hele Titanium’s expertise to deliver consistently outstanding performance. Step into the future of efficient metal recovery with us.

Cathodic Protection Anodes

ICCP Anodes

Step up your infrastructure protection with our elite ICCP Anodes. Crafted for unparalleled conductivity and lasting durability, they stand as your frontline defense against corrosion. Trust in Hele Titanium’s expertise to provide superior cathodic protection, safeguarding your assets for the future. Make the switch today for a more secure tomorrow.

cathodic protection cable

Cathodic Protection Cable 

Elevate your asset protection strategy with our robust Cathodic Protection Cable. Engineered to thrive in the harshest conditions, it’s your shield for critical assets such as pipelines, marine structures, and storage tanks. Reliability, extended asset longevity, and unmatched protection are just a cable away. Trust Hele Titanium to fortify your investments and guarantee lasting peace of mind.

Titanium Electrolyzer for Sodium hypochlorite generator

Titanium Electrolyzer

Step up your game with our advanced Titanium Electrolyzer. Engineered with a state-of-the-art MMO coating, it promises not just efficiency but unparalleled corrosion resistance. With Hele Titanium by your side, transform your operations and tap into untapped potential. Make the switch and witness a new horizon of performance.

Sacrificial Anode

Sacrificial Anode

Protect your investments with our cutting-edge sacrificial electrodes. Engineered for those who prioritize asset longevity and reduced maintenance costs, these anodes actively combat corrosion, amplifying the durability of your infrastructure. With Hele Titanium, ensure unparalleled safety and longevity for your assets. Seize the advantage; safeguard your future today.

Titanium Anode Manufacturer and Supplier in China

At Hele Titanium, understanding the unique demands of your project is our core focus. As a renowned manufacturer of titanium anodes, we are dedicated to providing precision and customization at every phase of your journey:

Custom MMO Wire Anodes for Your Specific Needs

Custom MMO Wire Anodes Tailored to Your Needs

  • Bespoke Specifications: Tailor the size, shape, and configuration to seamlessly fit your project’s requirements.
  • Choice of Coatings: Choose from Mixed Metal Oxide (MMO), platinum, or lead dioxide coatings to ensure maximum performance in your specific environment.
  • Electrode Variety: Select from rod, mesh, plate, or tube electrodes, each designed to optimize your electrochemical processes.
  • Voltage & Current Precision: Specify your exact needs for optimal electrochemical efficiency.
  • Coating Thickness Control: Determine the ideal coating thickness to strike the right balance between durability and performance.
  • Specialized Connectors: Customize end connectors or terminals for seamless integration into your systems.

Discover the comprehensive range of titanium anode solutions at Hele Titanium. Collaborate with our expert team to fine-tune every aspect to your exact specifications and enjoy superior technical support. Experience the Hele Titanium advantage: precision, expertise, and a commitment to excellence, all at your service.

Easily Tailor Your Titanium Anodes with Hele Titanium

Navigating the customization process has never been smoother. At Hele Titanium, we’ve streamlined the journey to obtaining your custom DSA anodes, removing the usual hurdles. Our effective four-step method ensures you have our full support at each stage:

Operating Conditions

Share the nuances of your operation. This includes details like electrolytes, temperature, average current densities, overall cell voltage, overpotential, and the projected service life.

Specify Application

Define the electrochemical processes you’re aiming for. Be it electrosynthesis, electrowinning, electroplating, electrochemical oxidation, disinfection, cathodic protection, or any other specialized process, we’ve got you covered.

Selecting Anodic Processes

Narrow down to the exact anodic process required, whether it’s oxygen gas evolution, chlorine gas evolution, mixed gas evolution, or electrochemical oxidation.

Drawing and Specifications

Submit your design and detail out the shape, dimensions, and measurements, ensuring the final anode aligns perfectly with your vision.

Why Choose Titanium Anodes from Hele Titanium?

As pioneers in the MMO titanium anode industry, we are committed to delivering excellence in every aspect. With decades of experience, we have provided top-notch anode solutions to various industries globally, building a reputation for innovation, superior quality, and unmatched performance.

  • Customer-Centric Solutions
    At Hele Titanium, we tailor every anode to your specific requirements, ensuring optimal performance and the highest level of satisfaction.
  • Future-Ready Technology
    Stay at the forefront with our technologically advanced MMO anodes. Designed to cater to both current and future demands.
  • Manufacturing Mastery
    With our state-of-the-art facilities and unwavering commitment to innovation, we deliver anodes that set new standards in corrosion protection.
  • Competitive Pricing
    Where quality meets affordability. Choose us for the finest titanium anodes, competitively priced to suit industries of all sizes.

FAQs About Titanium Anode

We’ve compiled the most frequently asked questions about our titanium anode for your convenience. However, should you have any additional questions, please don’t hesitate to contact us.

MMO stands for Mixed Metal Oxide. Our MMO titanium anodes are known for their unparalleled performance and durability in various electrochemical processes.

Titanium anodes are integral to industries like wastewater treatment, metal refining, electrolysis, electroplating, and more.

A longer lifespan translates to reduced replacement frequency, consistent output, and sustainable practices, all of which contribute to operational efficiency.

The quality and thickness of protective coatings determine the anode’s resistance to degradation and impact its electrocatalytic properties.

Operating conditions, coating quality, electrolyte composition, maintenance routines, current density, and mechanical stress are some factors.

We offer an extensive range, including sheets, plates, meshes, wires, and rods.

Yes, our MMO Titanium Anodes play an important role in pool disinfection processes.

We have a rich history and expertise in producing top-tier titanium anodes, offering customized solutions and ensuring quality, safety, and cost-effectiveness.

We have industry certifications such as ISO9001, which affirm our commitment to quality and compliance.

Absolutely! We pride ourselves on our flexibility and ability to tailor solutions to meet your unique requirements.

We have a knowledgeable team that can help guide you based on your specific needs, including factors like application, solution composition, and current density.

We offer robust after-sales services, including maintenance and repair, to ensure long-term satisfaction and optimal performance.

Our commitment to excellence, ability to produce our own raw materials, and adherence to rigorous quality standards set us apart.

Our capability to create our own raw materials allows us to offer competitive pricing, coupled with the longevity of our anodes, resulting in cost savings in the long run.

Comprehensive Guide to Purchasing Titanium Anodes

Elevate your operations with our high-quality MMO Titanium Anodes, ideal for chemical production, water treatment, cathodic protection, and other applications. This guide showcases the exceptional qualities of our products, designed to meet the demands of specific project needs and large-scale requirements across various industries.

We are dedicated to enhancing your purchasing experience, offering insights that facilitate informed and effective decisions. Partner with Hele Titanium to access anode solutions that exemplify excellence and innovation, backed by over a decade of manufacturing expertise.

Experience a seamless procurement process with us, where your projects benefit from our premium, custom-made anodes renowned for their durability and performance efficiency.

Chapter 1

What are Titanium Anodes?

Understanding Titanium Anodes

Titanium anodes, also known as dimensionally stable anodes (DSAs), are a type of electrode. They are recognized by various names, including dimensionally stable electrodes (DSE), precious metal-coated titanium anodes (PMTA), noble metal-coated anodes (NMCA), oxide-coated titanium anodes (OCTA), and activated titanium anodes (ATA).

Essentially, these anodes consist of a titanium base coated with a metal oxide layer. This coating engages actively in electrochemical reactions, with the titanium base acting as the electrical conductor.

These anodes employ a titanium substrate, in forms like mesh, plate, strip, rod, or tube, to enhance their electrochemical properties. The substrate is coated with a thin layer of mixed metal oxides (MMOs), including RuO2, IrO2, PbO2, and Ta2O5.

These titanium anodes are commonly referred to as “MMO anodes” due to the widespread use of MMO coatings.

Chapter 2

History of the Titanium Electrode

History of the Titanium Electrode

The 1960s saw a revolution in electrode technology, led by Dr. H. Breer from the Netherlands. He developed the ruthenium-titanium coated titanium electrode, marking a significant breakthrough.

To fabricate the electrode, he employed titanium as the base, coating it with an alcoholic mixture of ruthenium and titanium salts. The sintering process produced a durable Ru-TiO2 solid solution layer, tightly bonding to the titanium base.

The introduction of the Ruthenium-Titanium electrode offered a significant alternative to graphite electrodes. Graphite electrodes often distorted with use, whereas the new titanium-based variant, leveraging valve metal titanium’s inherent robustness, resolved these issues.

This marked the beginning of the titanium electrode revolution. Over time, innovation has led to the development of various chemical formulations that endow titanium electrodes with diverse characteristics and capabilities.

Currently, titanium electrodes, referred to as titanium oxide-coated anodes (MMO) or DSA anodes, play a crucial role in numerous industries. Their design, featuring a titanium substrate in various forms like wire, rod, tube, plate, or mesh, with a noble metal coating, ensures enhanced electrocatalytic activity, improved electrical conductivity, and sustained resistance to oxidation.

Chapter 3

Advantages of Titanium Anodes

Advantages of Titanium Anodes

Compared to traditional graphite and lead anodes, titanium anodes offer a range of significant advantages:

  • Dimensional Stability: Titanium anodes ensure consistent spacing during electrolysis, resulting in uniform cell voltage.
  • Superior Catalytic Performance: These anodes exhibit increased catalytic activity and operate at lower voltages.
  • Energy Efficiency: The lower operating voltage of these anodes leads to a 10%-20% reduction in DC power consumption.
  • Extended Durability: These anodes, resistant to chlorine and alkali corrosion, can last 5-7 years, far outlasting the eight-month lifespan of graphite anodes.
  • Eco-friendly: Titanium anodes do not dissolve during electrolysis, thus eliminating contamination risks for electrolyte and cathode products.
  • Augmented Electrolytic Performance: These anodes improve current density and electrolytic efficiency.
  • Robust Corrosion Resistance: Coated with precious metals such as iridium and ruthenium, these anodes exhibit superior corrosion resistance.
  • Enhanced Operational Efficiency: These anodes prevent problems such as lead anode deformation and short circuits, facilitating smoother operations.
  • Lightweight Design: Titanium anodes are much lighter than graphite ones, reducing labor during use.
  • Manufacturing Flexibility: The titanium base material’s adaptability to fabrication and machining simplifies the production process of these anodes.

Summary: In conclusion, titanium anodes stand out for their robustness, efficiency, and environmental friendliness, offering a comprehensive suite of benefits that make them superior to traditional anodes in various industrial applications.

Chapter 4

Titanium Anode Geometry Design Guide

Titanium Anode Geometry Design Guide

At Hele Titanium, we specialize in creating custom-designed titanium anodes, perfectly suited to our clients’ distinct requirements. Partnering with leading contractors and metal fabricators, we’re dedicated to producing top-tier anodes in a variety of configurations, including:

  • Sheets: Offered in both square and rectangular patterns.
  • Strips, Foils, and Plates: Precision-engineered for exact needs.
  • Metal Forms: Choices range from expanded metal and meshes to corrugated plates and perforated designs.
  • Rod Structures: A diverse selection, from wires and rods to discs, bars, and tubes.

Our design approach prioritizes a robust bond between the titanium substrate and its active coating. By optimizing the electrode’s surface area, we ensure enhanced electrocatalytic efficiency and optimal current densities. This focus on design efficiency translates to heightened productivity and cost savings for our clientele.

Chapter 5

How to Select the Idea Titanium Anode?

How to Select the Right Titanium Anode?

Selecting the perfect titanium anode is a critical decision in designing and operating electrochemical systems. The right anode enhances the efficiency and effectiveness of the electrochemical process and ensures longevity and reliability. To make an informed selection, it’s essential to consider a range of factors that influence anode performance and compatibility with your specific application. During the customization process, evaluate each aspect meticulously to align with the technical demands and operational conditions of your system.

  • Application Context: Identify the specific domain of the titanium electrode’s function, such as non-ferrous metal electrolysis, chlorine salt electrolysis, or seawater electrolysis.
  • Solution Composition: The anode design significantly depends on the solution’s composition. Understanding the primary constituents aids in optimal anode selection.
  • Current Density: Evaluate the current flow per unit area to maximize the titanium anode’s potential.
  • Temperature and pH Values: The operating temperature and pH range are crucial in selecting the appropriate anode type.
  • Titanium Electrode Variants: Explore options such as Ruthenium Iridium Oxide, Iridium Tantalum Oxide coated, or platinized titanium electrodes, based on the application’s requirements.
  • Operational Life Expectations: Match the expected service life of the anode with your project’s timeline.
  • Financial Considerations: Collaborate with our experts to secure a solution that satisfies both your technical needs and budget constraints.

At Hele Titanium, we prioritize finding the right titanium anode for your specific needs, guiding you toward an informed choice for enhanced performance and efficiency.

Chapter 6

Understanding Titanium Electrode Pricing

Understanding titanium electrode pricing involves knowing the factors that affect its cost. As a leading titanium anode manufacturer, Hele Titanium is dedicated to clarifying each factor affecting titanium electrode pricing.
Decoding the price

  • Titanium Substrate Cost: The cost of titanium substrates, including plates, sheets, meshes, and rods, directly correlates with the market rate. As market dynamics and demand change, titanium substrate costs, benchmarked by the Shanghai Metal Market (SMM), adjust accordingly.
  • Precious Metal Expense:  To achieve unparalleled quality and enhance the lifespan of electrodes, a predominant segment (around 80%) of MMO titanium anode manufacturers, including Hele Titanium, employ Heraeus precious metals for electrode coating. The cost of these metals is dynamic and subject to market fluctuations. For specific price details, please consult the Heraeus precious metal pricing chart directly via their website.
  • Manufacturing Overheads: Despite fluctuations in titanium substrate and precious metal costs, manufacturing expenses stay relatively stable. However, factors such as workforce compensation and managerial costs can cause slight variations.

Hele Titanium advocates for transparent and competitive pricing. When you share your requirements with us, you can expect a detailed quote tailored to your needs. Contact us to find the best titanium electrode solutions at competitive prices.

Chapter 7

How Do We Craft Our Industry-Leading Titanium Anodes?

At Hele Titanium, we specialize in converting raw titanium into superior titanium anodes, embodying our dedication to excellence and quality. Our refined production process guarantees anodes that surpass industry standards in electrocatalytic efficiency and corrosion resistance. Here is a detailed exploration of our anode production methodology:

Substrate Preparation1. Substrate Preparation

Initiating our process, we meticulously select the appropriate titanium substrate from options like plates, sheets, meshes, or rods, guided by the specific requirements outlined in the client’s machining blueprints. This step is crucial as it sets the foundation for the anode’s final characteristics.

 

 


Titanium Substrate Sandblasting2. Sandblasting Process

Through sandblasting, we enhance the substrate’s surface area, optimize its texture, and eliminate any oxidation remnants. This preparation ensures a uniform and receptive surface for the coating, characterized by a matte finish that enhances coating adhesion and electrochemical performance.

 

 

 


Laser Cutting3. Laser Cutting

We employ state-of-the-art laser cutting technology to shape the titanium with unparalleled precision, resulting in clean, burr-free edges. This method preserves the substrate’s structural integrity, preventing deformations or fractures and ensuring dimensional accuracy.

 

 

 


Welding4. Welding

The welding process is pivotal in forming the titanium’s ultimate structure. Our skilled technicians use argon arc welding for general substrates, spot welding for plates and sheets, and extensive welding for meshes, tailoring the approach to each substrate’s specifications to achieve optimal structural integrity.

 

 


Acid Pickling5. Acid Pickling

In the acid pickling stage, the substrate is submerged in a 10% oxalic acid solution and heated to a precise temperature to ensure thorough cleansing. This meticulous process removes all oxide films and impurities, resulting in a pristine substrate essential for the subsequent coating phase.

 

 

 


Precious Metal Solution Preparation6. Precious Metal Solution Preparation

We custom-design the precious metal solution based on the anode’s intended application environment, carefully adjusting the mixture to enhance the anode’s operational quality and extend its lifespan. This bespoke approach ensures the anode’s performance is precisely aligned with application requirements.

 

 


Titanium Electrode Coating7. Titanium Electrode Coating Process

The application of precious metals such as Ruthenium-Iridium, Iridium-Tantalum, or Platinum to the substrate is performed with exacting precision. Manual brushing in multiple passes achieves a homogeneous coating thickness of 8-10μm, ensuring consistent electrocatalytic properties across the anode surface.

 

 


Sintering and Annealing8. Sintering and Annealing

Next, the substrate undergoes sintering in a custom-designed furnace, where a specific temperature profile develops a crystalline structure, enhancing the bond strength and electrochemical performance. Annealing follows, methodically reducing hardness, relieving internal stresses, and refining the grain structure, culminating in a material optimized for endurance and functionality.

 

 


Quality Testing (Life Enhancement Test)9. Quality Testing (Life Enhancement Test)

Each anode undergoes stringent testing to validate its durability and performance, adhering to rigorous industry standards. This comprehensive evaluation ensures that every anode is equipped for long-term operational stability and reliability.

 

 

 


Packaging10. Packaging

After successfully passing all quality control checks, the anodes are meticulously packaged to preserve their integrity during transportation, ensuring they reach our clients in impeccable condition, ready for deployment.

 

 

 


Selecting Hele Titanium as your partner guarantees access to a legacy of precision, quality, and innovation. Our titanium anodes stand as a testament to enduring performance and unparalleled quality, setting the benchmark in the industry.

Chapter 8

Why Is Titanium the Optimal Choice for Anode Construction?

 

Titanium excels in the field of material science, emerging as the premier choice for anode materials. Below we detail titanium’s superior attributes and how Hele Titanium optimizes these features:

The Titanium Advantage

  • High Melting Point: Titanium’s ability to endure extremely high temperatures ensures reliable and consistent performance under the most demanding conditions. This quality establishes it as a dependable material for anode construction.
  • Exceptional Corrosion Resistance: Titanium naturally resists corrosion in various environments, including both acidic and alkaline. This resistance contributes to its durability and ensures a prolonged lifespan, even in the most challenging conditions.
  • Outstanding Durability and Thermal Stability: The intrinsic strength of titanium, combined with its ability to maintain performance across a range of temperatures, makes it an adaptable and trustworthy material for numerous applications, solidifying its status as an exceptional anode material.

Leveraging these remarkable properties, Hele Titanium designs and produces anodes that not only meet but also surpass the performance expectations for a variety of applications, guaranteeing superior functionality and extended durability.

Chapter 9

Titanium Anode Types and Their Applications

Understanding the various types of titanium anodes is essential for achieving optimal results. Titanium anodes are categorized into five main types, each distinguished by a unique surface catalytic coating. This section explores these types and their applications, highlighting how Hele Titanium enhances their effectiveness.

Ruthenium-Coated Titanium Electrode

Ruthenium Iridium Titanium Anodes

“Exceptional Performance, for Chlorine Evolution”

Ruthenium-iridium-coated titanium electrodes are known for their high catalytic efficiency and strong antioxidant properties, ideal for chlorine generation in various sectors. Key applications include:

  • Chlorine Salt Electrolysis: Used in the production of sodium chlorate and sodium hypochlorite.
  • Seawater Electrolysis: Applied in desalination and aquaculture for water purification and maintenance.

Different ruthenium coatings, like Ru-Ti, Ru-Ir-Ti, and others, are tailored to specific application needs. The standard mix often consists of 8g ruthenium and 2g iridium per square meter with an 8-micron thickness, providing a robust and efficient performance.

Hele Titanium customizes these anodes with coatings like Ru-Ti and Ru-Ir-Ti, optimizing their efficiency and lifespan for these specific applications.


Iridium-Coated Titanium ElectrodeIridium Tantalum Titanium Anodes

“Oxygen Evolution Experts”

Iridium tantalum electrodes are renowned for their performance in environments with strong oxidizing agents, serving in:

  • Manufacture of Metal Foils: Critical in creating thin, high-quality metal sheets for various industrial uses.
  • Non-Ferrous Metal Electrolysis and Recovery: Employed in the extraction and recycling of valuable metals, enhancing efficiency and sustainability.
  • Industrial Electroplating: Key in applying durable and protective metal coatings to objects, improving their longevity and appearance.
  • Cathodic Protection: Essential for preventing corrosion in infrastructures like pipelines and storage tanks.
  • Electrodialysis: Used in separating ions for water desalination and resource recovery, proving their versatility and efficiency.

Hele Titanium’s Iridium-Tantalum Titanium Anodes are engineered for durability and performance, meeting the demands of these diverse applications.


Platinum-Plated Titanium ElectrodePlatinum Coated Titanium Anodes

“Versatile and Reliable”

Platinized titanium anodes known for their excellent electrocatalytic activity and corrosion resistance, have a broad spectrum of applications across various industries. The expanded list of their applications includes:

  • Electrolytic Water Treatment: Utilized in producing high-purity water, these anodes are critical in removing impurities and contaminants, ensuring water quality for industrial, medical, and laboratory uses.
  • Seawater Electrolysis: They play a vital role in the electrolysis of seawater, a process that desalinates water and produces chlorine, used in disinfection and various chemical processes.
  • Organic Synthesis: In the realm of organic chemistry, platinized anodes are employed in electrochemical synthesis reactions, facilitating the production of organic compounds through controlled and efficient redox reactions.
  • Cathodic Protection: These anodes are instrumental in protecting metal structures from corrosion, especially in marine environments, pipelines, and storage tanks, by providing a sacrificial layer that prevents the deterioration of the base metal.
  • Hydrogen Production: In the field of electrolytic water hydrogen production, platinum-coated titanium anodes are used to split water molecules into hydrogen and oxygen, contributing to the generation of clean energy.

Hele Titanium’s platinum-coated anodes, with their diverse applications, demonstrate the material’s versatility and efficiency in enhancing the performance and sustainability of various industrial processes.


 

Lead Dioxide Titanium AnodesLead Dioxide Titanium Anodes

Oxidation and Corrosion Resistance

Lead Dioxide Titanium Anodes Known for their robust oxidation and corrosion resistance, Lead Dioxide Titanium Anodes are particularly effective in:

  • Electroplating and Electrolysis Industry: Playing a critical role in metal finishing and water treatment processes, where their durability and efficiency in oxidative environments are paramount.

With a commitment to quality and innovation, Hele Titanium ensures these anodes meet the high standards required for effective performance in challenging conditions, leading to improved process efficiency and reliability.

Chapter 10

Titanium Anode Comparison: Ru-Ir vs. Ir-Ta vs. Pt-Ti

This comparison delves into the distinct characteristics and applications of Ruthenium-Iridium (Ru-Ir) coated anodes, Iridium-Tantalum (Ir-Ta) coated anodes, and Platinized Titanium (Pt-Ti) anodes. By examining their specific properties, usage areas, and performance metrics, we aim to provide a comprehensive understanding of these anode types, facilitating informed decision-making for their optimal use in various industrial processes.

Aspect Ruthenium Iridium Coated Anodes Iridium Tantalum Coated Anodes Platinized Titanium Anodes
Corrosion Resistance Exceptional Balanced Good
Durability High Durable Moderate
Substrate Material Titanium Titanium Titanium
Coating Materials Ruthenium, Iridium Iridium, Tantalum Platinum
Conductivity High Moderate Moderate
Applications Chlor-alkali production, Electrolytic water treatment Electroplating, Electrowinning, Organic synthesis Electroplating, Metal electrowinning, Electrolytic recovery
Benefits Excellent lifespan, Ideal for aggressive environments Cost-effective solution, Suitable for various applications Catalytic properties accelerate reactions, Reduced energy consumption
Challenges Higher cost, Overkill for less aggressive environments Moderate lifespan, May not suit extreme conditions Requires periodic maintenance, Limited lifespan compared to coated anodes
Usage Lifespan Long Moderate Moderate
Cost Higher Moderate Moderate

Note: The provided information is based on general characteristics and applications of each type of anode. Specific performance can vary based on manufacturer, composition, and usage conditions. Always consult with experts and suppliers for detailed information tailored to your requirements

Chapter 11

Titanium Anode Lifespan and Its Impact on Industry Success

 

The durability and reliability of titanium anodes in electrochemical applications are pivotal, marking their significance in processes like electroplating and wastewater treatment. The lifespan of these anodes directly influences the operational efficiency and environmental sustainability of such processes.

Significance of Lifespan in Industrial Applications

The longevity of titanium anodes plays a vital role in:

  • Cost-Efficiency: Extended lifespan correlates with fewer replacements, leading to decreased downtime and reduced operational expenses.
  • Consistent Output: A durable anode ensures sustained performance, crucial for maintaining high-quality output and process efficiency.
  • Sustainability: The robust nature of these anodes supports eco-friendly practices by lessening the frequency of replacements and associated waste.

Understanding the Life of Titanium Anodes


Determinants of Titanium Anode Lifespan

The life expectancy of titanium anodes is shaped by several factors:

  • Operating Conditions: The combination of electrolyte composition, temperature, and current density can impact both corrosion rates and lifespan.
  • Coating Quality: High-quality coatings, such as those made from platinum or iridium, are essential for minimizing degradation.
  • Electrolyte Composition: Aggressive electrolytes may accelerate corrosion, diminishing the anode’s lifespan.
  • Maintenance: Consistent inspections and maintenance are imperative for optimal anode performance.
  • Current Density: Compliance with the recommended current densities can prevent undue wear and extend anode life.
  • Mechanical Stress: Physical factors like vibration or thermal expansion can compromise the anode’s structural and coating integrity.
  • Electrolyte Flow: Ensuring proper flow can avert the buildup of corrosive substances, thus protecting the anode.

Understanding and managing these factors is crucial for maximizing the lifespan of titanium anodes, which in turn enhances process efficiency, reduces costs, and promotes sustainable operations.


Customized Anode Solutions for Enhanced Performance

To accommodate the varying demands of industrial operations, our portfolio includes Mixed Metal Oxide (MMO) titanium anodes, available in four distinct performance grades:

  • Light Utilization (LU): Suitable for low-corrosive or intermittent use, LU anodes offer cost-effective performance for lighter applications.
  • Moderate Service Life (MSo): Ideal for regular use under moderate conditions, MSo anodes balance durability and cost, fitting standard environments.
  • High Service (HS): Designed for continuous operation in harsh settings, HS anodes deliver superior durability and longevity, perfect for demanding applications.
  • Heavy Utilization (HD): Built for extreme conditions, HD anodes provide the utmost durability and performance in highly corrosive or high-temperature situations.

By offering a range of anode types, we enable industries to select the optimal solution that aligns with their specific operational requirements and budget constraints. This tailored approach ensures that each customer can achieve the best balance of performance, cost, and lifespan, thereby enhancing the overall efficiency, sustainability, and cost-effectiveness of their processes. Our commitment to providing versatile and durable titanium anodes reflects our dedication to advancing industrial success and promoting sustainable practices.

Chapter 12

 Precautions for Handling and Use of Titanium Electrodes

 

Titanium electrodes are essential in various industrial applications, acting as insoluble anodes with a noble metal oxide coating on a titanium substrate, created through high-temperature sintering. Vital for electroplating, water treatment, and chlor-alkali production, their stability, conductivity, and corrosion resistance significantly impact operational efficiency, product quality, and sustainability. To maximize their potential and longevity, it is crucial to follow specific handling and usage guidelines.

  • Identification: The cathode side of a titanium electrode is black, while the uncoated side, often bluish or gray, presents a titanium dioxide layer and lacks electrode properties.
  • Handling: Transport, install, and dismantle the pickled titanium electrode substrate with caution. Use clean gloves and touch only the uncoated areas to prevent contamination.
  • Electrolyte Composition: Ensure the electrolyte is devoid of cyanide and fluoride ions to avoid titanium structure degradation and severe corrosion.
  • Filtering: Employ a filtration system before the electrolyte enters the cell to prevent metal particle accumulation and potential short circuits.
  • Metal Recovery: In the electrolytic recovery of metals like gold, silver, nickel, and cobalt, avoid dense cathode attachments and initiate with copper stripping to prevent anode-cathode short circuits.
  • Gap Adjustment: Maintain an anode-cathode distance of 3-25mm as per production needs, and avoid using the inverted pole setup.
  • Immersion: When not in use, especially for long periods, do not immerse the electrode in solution. Maintain a protective current of around 5A.
  • Cleaning: Refrain from using nylon or abrasive materials for electrode surface cleaning.
  • Temperature Control: Keep the electrolyte temperature within 25-40℃, possibly through a heat exchanger.
  • Current Density: Limit the operational current density to under 2000A/m² to preserve anode life.
  • Electrolysis Cell Activation: Gradually increase the current during cell activation, avoiding sudden surges or stops.
  • Cleanliness: Maintain anode cleanliness, free from oil and other contaminants, to ensure efficient electrolysis and longevity.
  • Observation: Note that conductivity may vary among titanium anodes under the same conditions; familiarize yourself with their performance during initial use.
  • Maintenance: Regular service cycle extension can enhance production stability.

Adherence to these guidelines will optimize the efficiency and lifespan of titanium electrodes across various industrial operations.

Chapter 13

How to Clean Titanium Anodes?

how to clean titanium anodeCleaning a titanium anode is essential to maintain its efficiency, especially when used in electrochemical processes such as electroplating or water treatment. Over time, titanium anodes can accumulate deposits, impurities, or contaminants that can affect their performance. Here’s a general procedure for cleaning a titanium anode:

  • Turn off the Power Supply: Ensure that the power supply to the anode system is disconnected to prevent any electrical hazards.
  • Remove the Anode: Carefully detach the anode from its system, which may involve loosening fasteners or disconnecting electrical connections.
  • Initial Rinse: Gently rinse the titanium anode with clean water to remove loose surface dirt and debris, preventing scratches during the cleaning process.
  • Chemical Cleaning for Gentle Cases:
    • Mild Detergent Solution: Prepare a warm solution of mild detergent and soak the anode briefly. This can help loosen and dissolve deposits.
    • Soft Brush Scrubbing: Use a soft brush or cloth to gently scrub the anode’s surface, focusing on areas with visible deposits.
    • Rinse Thoroughly: Rinse the anode with distilled water to remove any detergent residue.
  • Chemical Cleaning for Tough Deposits:
    • Dilute Hydrochloric Acid Solution: For more stubborn deposits, prepare a 10% hydrochloric acid (HCl) solution. Soak the anode in this solution, monitoring the process closely to prevent over-exposure.
    • Timed Soaking: The duration of the soak should be adjusted based on the severity of the deposits. It’s crucial to avoid prolonged soaking to prevent potential damage to the MMO coating.
    • Acid Rinse: After soaking, thoroughly rinse the anode with distilled water to remove any acid residue, ensuring no chemical remains on the surface.
  • Inspect the Anode: Check the anode for any signs of damage or excessive wear, especially in the MMO coating. If significant damage or wear is observed, consider recoating or replacing the anode.
  • Dry the Anode: Allow the anode to air dry completely, ensuring that all parts, especially electrical connections, are moisture-free.
  • Reinstall the Anode: Reattach the anode to the system securely, ensuring all electrical and mechanical connections are properly made.
  • System Check: Reactivate the power supply and conduct a system check to confirm the anode is functioning properly.

This comprehensive cleaning procedure helps maintain efficiency and extend titanium anodes’ life, especially in demanding applications like chemical processing and cathodic protection.

Chapter 14

Applications of Titanium Anodes

Titanium anodes, particularly MMO (Mixed Metal Oxide) types, are prominent in electrochemical processes due to their exceptional performance and durability. They play a critical role in various industries, such as wastewater treatment, metal refining, electrolysis, and electroplating. The superior corrosion resistance and catalytic activity of titanium anodes render them ideal for demanding industrial environments. With the growing need for efficient and enduring solutions, titanium anodes increasingly affirm their significance in contemporary industrial applications.


Chlor-alkali Industry, Chlorate Industry Electrolytic Production

Chlor alkali industry

In the chlor-alkali sector, Mixed Metal Oxide (MMO) titanium anodes play a pivotal role in the electrolysis of sodium chloride (NaCl) solutions, producing chlorine, hydrogen, and sodium hydroxide. These anodes, integral to industries like light manufacturing, textiles, metallurgy, petrochemicals, and utilities, are central to chlor-alkali operations.

Comprising a titanium base with coatings of oxides such as iridium and tantalum, MMO anodes are prized for their superior electrocatalytic performance and ability to withstand the corrosive environments encountered in chlorine and caustic soda production. Their durability and extended service life not only provide cost efficiency but also operational reliability, rendering them essential in diaphragm, ion-exchange membrane, and mercury electrolysis processes. These processes are crucial for producing chlorine gas, hydrogen, and caustic soda.

In addition, MMO anodes are vital in the chlorate industry for generating key compounds, thereby highlighting their role in improving the efficiency and reliability of electrochemical processes in these sectors.


Cathodic Protection Anode

Cathodic Protection

Mixed Metal Oxide (MMO) titanium anodes play a pivotal role in the cathodic protection industry, safeguarding infrastructure against corrosion in harsh environments. These anodes are essential for the longevity and safety of steel structures exposed to marine, terrestrial, and varied industrial conditions. Their efficacy stems from their robustness and ability to withstand aggressive corrosive processes, despite the challenges posed by natural and industrial environments.

In cathodic protection, MMO anodes are utilized in two primary methods: Impressed Current Cathodic Protection (ICCP), where they help establish a protective cathodic surface over metal structures, and Sacrificial Anode Protection, where they act as a sacrificial element to prevent structural corrosion. These techniques are integral to maintaining the structural integrity of submerged and buried installations like ship hulls, offshore platforms, and pipelines.

The application of MMO titanium anodes extends across various domains, including marine, industrial, and terrestrial environments. They are crucial in preventing corrosion in ships, docks, storage tanks, pipelines, and cooling systems exposed to saline, alkaline, or soil conditions. This broad utility underscores the anodes’ importance in ensuring the durability and operational safety of essential infrastructure worldwide.


Gold Plating, Galvanized Tin Plating, Steel Plate

Electroplating Industry

The electroplating industry commonly engages in processes such as gold plating, galvanizing steel plates, nickel plating, chrome plating, silver plating, copper plating, zinc plating, and cadmium plating.

Titanium electrodes, especially Mixed Metal Oxide (MMO) titanium anodes, are increasingly recognized in the electroplating sector for their exceptional conductivity and corrosion resistance. They outperform lead anodes in longevity, operating reliably for over 4000 hours, and offer cost-effectiveness. This performance highlights a worldwide trend towards improving electroplating processes for zinc and tin.

In countries like Japan, the United States, Germany, and others, titanium anodes are acclaimed for reducing energy consumption in electroplating and enabling higher current densities. These capabilities are essential for manufacturing steel plates with thicker zinc or tin layers. The integration of MMO titanium anodes into electroplating signifies substantial progress, optimizing the process, elevating product quality, and promoting environmental sustainability by lowering energy use and waste.


PCB Electronic Circuit Board Factory Etching Waste Liquid Recovery

Printed Circuit Board Manufacturing

Printed Circuit Board (PCB) manufacturing entails a sophisticated process of forming intricate electrical pathways on insulated substrates to mount and interconnect electronic components. This procedure includes stages such as design, pattern transfer, etching, and electroplating, all aimed at producing functional and dependable PCBs.

Mixed Metal Oxide (MMO) titanium anodes are critical in the electroplating phase of PCB manufacturing. Their superior conductivity and corrosion resistance qualities are crucial for the precise deposition of metals like copper, which are fundamental in forming the PCB’s conductive traces.

The durability and efficiency of MMO anodes facilitate consistent metal layering, imperative for the detailed circuit designs and high-quality standards required in PCB production. Their extended service life and stability under electroplating conditions make them a preferred choice, significantly contributing to the reliable and economical manufacturing of PCBs.


Sodium Hypochlorite Industry

Sodium hypochlorite, a potent oxidizing agent, is esteemed for its effectiveness, wide-ranging efficacy, and safety as a sterilizing and virucidal substance. It possesses formidable antimicrobial attributes, serving as an alternative to traditional oxidizers such as bleaching powder.

Analytical chemistry reveals that sodium hypochlorite, at parts per million (ppm) concentrations in water, predominantly hydrolyzes into hypochlorous acid with an efficiency exceeding 99%. During sterilization and virucidal processes, hypochlorous acid impacts not only the cell walls and viral envelopes but also infiltrates organisms, attributed to its small, non-charged molecular form. It undergoes oxidative reactions with organic macromolecules like proteins, nucleic acids, and enzymes in pathogens, thus neutralizing them.

In this regard, Mixed Metal Oxide (MMO) titanium anodes are essential for the electrochemical generation of sodium hypochlorite. Utilized in the electrolysis of seawater or saline solutions, MMO anodes expedite sodium hypochlorite production. Their durability and electrocatalytic efficiency render them optimal for this purpose, enabling the effective and economical synthesis of sodium hypochlorite for disinfection and sterilization applications.


Sewage Treatment

Wastewater Treatment

Wastewater, originating from industrial, agricultural, and domestic sources, contains diverse constituents like organic materials, chemicals, heavy metals, and pollutants. Its treatment is vital to prevent environmental degradation, safeguard public health, and enable water recycling. Effective management of wastewater is essential for reducing pollution’s ecological impact and promoting sustainable water usage.

MMO (Mixed Metal Oxide) titanium anodes play a crucial role in the electrochemical treatment of wastewater. These anodes are employed in electrolytic processes to eliminate contaminants. Electrochemical treatment, powered by MMO anodes, utilizes both direct and indirect electrolysis to decompose pollutants, diminish toxicity, and reclaim valuable metals, making the water suitable for discharge or reuse.

The connection between MMO anodes and wastewater treatment is significant. The distinct characteristics of MMO anodes, including high conductivity, corrosion resistance, and longevity, render them ideal for processing various wastewater types, such as industrial runoff, cyanide-laden waste, and domestic sewage. Their efficiency in pollutant breakdown and resource recovery highlights the critical function of MMO titanium anodes in enhancing wastewater treatment methods.


PCB Etching Waste Recovery

PCB (Printed Circuit Board) Etching Waste Recovery is essential for reducing environmental impact and reclaiming valuable metals. In PCB production, etching removes surplus metal to create the necessary circuit patterns, producing waste containing metals like copper. The recovery of these metals mitigates raw material extraction and diminishes hazardous waste disposal, contributing to sustainable manufacturing.

MMO (Mixed Metal Oxide) titanium anodes are crucial in the electrochemical recuperation of metals from PCB etching waste. Their superior conductivity, durability, and corrosion resistance render them suitable for electrochemical cells aimed at metal recovery. These anodes enable the oxidation reactions required to reclaim metals from the waste solution, thereby restoring them to a utilizable state.

The link between MMO titanium anodes and PCB Etching Waste Recovery is profound. Leveraging the electrochemical properties of MMO anodes allows for the efficient recovery of metals from PCB etching waste, promoting resource sustainability and minimizing environmental pollution. This practice improves resource efficiency and facilitates the environmentally friendly disposal and recycling of industrial waste.


Circulating Water Softening

Circulating Water Softening

Water softening is a critical process within circulating systems, primarily due to its profound impact on equipment efficiency and lifespan. The presence of calcium and magnesium ions in these systems often leads to scaling, causing blockages and increased resistance in pipelines and equipment. This scaling not only diminishes flow rates but also obstructs heat transfer in boilers, resulting in energy inefficiency and reduced operational performance. Furthermore, scaling fosters bacterial growth, posing health hazards and polluting water sources.

To combat these challenges, various water softening techniques are employed, with MMO (Mixed Metal Oxide) titanium anodes playing a central role. These specially designed anodes operate on cathodic reduction principles and are strategically positioned within circulating water pools. They attract and adsorb calcium and magnesium ions from the water onto their surfaces, effectively removing metal ions and preventing scaling while preserving the desired water softness.

An alternative method involves passing water through descaling units before reintroduction into the system. These units act as effective filters, adsorbing calcium and magnesium ions and preventing downstream scaling issues. Both approaches, facilitated by MMO titanium anodes, ensure efficient water softening, safeguarding equipment, conserving energy, and inhibiting bacterial proliferation, thereby enhancing circulating systems’ overall performance and longevity.


Electrolytic Copper Foil

Electrolytic Copper Foil

Copper foil holds significant importance in industries like electronics and instrumentation, with increasing demand driven by technological advancements and automation, particularly in the realm of large-scale integrated circuits. This heightened demand also comes with stricter quality requirements for copper foils, highlighting their crucial role in ensuring reliable and high-performance electronic components.

In the electrolytic production of copper foils, titanium anodes are essential components that significantly influence the process’s efficiency and quality. Titanium anodes serve as positive electrodes during electrolysis, facilitating the deposition of copper ions onto the cathode to form the desired copper foil. Their excellent conductivity, corrosion resistance, and durability play a vital role in maintaining stable and effective electrolysis, thus impacting the uniformity and quality of the resulting copper foils.

In summary, titanium anodes play a pivotal role in the electrolytic production of copper foils, ensuring efficient and stable electrolysis processes that lead to high-quality, uniform copper foils. This relationship underscores the critical importance of titanium anodes in enhancing the reliability and performance of copper foil production for various industrial applications, particularly in electronics and instrumentation sectors.


Electrolytic Function Water

Electrolytic Function Water

Functional water is a type of water that has been treated to acquire various beneficial properties. It is produced through processes like electrolysis, which alters the water’s composition to enhance its functionality. Functional water includes types with antimicrobial properties, which are effective in sterilization and disinfection without causing secondary pollution. These enhanced waters are used in a range of applications, from medical treatments and health improvement to cleaning and disinfection in various industries, showcasing their versatility and importance.

Titanium anodes, particularly those coated with precious metals, are crucial in the production of functional water through electrolysis. The electrochemical process facilitated by these anodes breaks down water molecules, creating potent oxidizing agents like hypochlorous acid and hydroxyl radicals that contribute to the water’s functional properties. The durability and conductivity of titanium anodes, enhanced by precious metal coatings, allow for efficient and sustained electrolysis, making the production of high-quality functional water feasible on a commercial scale.

In summary, the relationship between titanium anodes and functional water is integral to the effectiveness of electrolysis in producing water with enhanced properties. Titanium anodes, with their superior electrochemical characteristics, are key to generating functional water that meets the demands of various applications, from healthcare to industrial processes. This synergy underscores the importance of advanced materials and technologies in improving water treatment solutions and their broader implications for environmental and public health.


Pool Disinfection

Pool Disinfection

Disinfecting swimming pools is crucial for maintaining their cleanliness and safety, ensuring they remain free of harmful microorganisms. Traditional methods typically employ chlorine to eliminate bacteria and viruses, necessitating continuous monitoring and potentially irritating users’ skin and eyes. Consequently, there is a shift towards alternative disinfection technologies that offer efficacy with fewer adverse effects.

In this context, titanium anodes coated with Mixed Metal Oxide (MMO) have gained prominence in pool disinfection. These anodes operate via electrolysis, a process that electrically charges water as it flows over the anode, resulting in the formation of hypochlorous acid in the pool. This acid, a powerful disinfectant, effectively eradicates pathogens. Utilizing MMO-coated titanium anodes enhances chlorine production’s stability and efficiency, curtailing manual chemical management and reducing harmful byproducts.

In summary, employing MMO-coated titanium anodes in pool disinfection marks a significant progress in pool maintenance technology. Such systems are a safer, more effective, and eco-friendlier alternative to conventional chemical-based methods. Automating disinfectant production and minimizing external chemical use, titanium anode systems enhance swimming pool quality and safety, positioning them as the superior choice for contemporary pool sanitation.


Chapter 15

How to Choose the Right Titanium Anode Supplier?

 

Choosing the right titanium anode supplier is a pivotal decision that directly impacts the efficiency and success of your industrial processes. Whether you need these anodes for industrial applications or specific projects, making an informed selection is crucial. Here are some valuable tips that will guide you through key factors to consider when choosing your titanium anode supplier, ensuring you partner with a provider capable of meeting your specific requirements:

  • Prioritize Certified Suppliers: Look for suppliers with relevant industry certifications, such as ISO9001, that confirm their products meet high standards set by regulatory bodies. Certifications demonstrate a commitment to quality and compliance.
  • Diverse electrode offerings: Choose suppliers that offer a wide range of titanium electrodes for different applications. This demonstrates their expertise and ensures the availability of the components you need.
  • Comprehensive after-sales support select: suppliers that offer robust after-sales services, including maintenance and repair, to ensure long-term satisfaction and optimal performance.
  • Focus on safety partner:  with suppliers who proactively comply with safety regulations to ensure their products meet the latest industry standards for safety and compliance.
  • Reputation and Reviews: Consider a supplier’s reputation through customer reviews and references that indicate their reliability and ability to deliver quality products and services.
  • Expertise and support Evaluate:  the supplier’s technical knowledge, as their expertise can help you select the right titanium electrodes for your specific needs.
  • Customization Flexibility: Choose suppliers who are willing to customize electrodes to meet your unique requirements, whether for special applications or custom dimensions.
  • Transparent pricing and communication: suppliers that provide clear pricing information and effective communication to avoid hidden costs and ensure a smooth relationship.

In conclusion, selecting the right titanium anode supplier involves careful consideration of their certifications, product range, after-sales support, safety compliance, reputation, technical expertise, customization capabilities, and pricing transparency. By prioritizing these factors, you can establish a partnership with a supplier that not only meets your immediate needs but also supports your long-term business objectives.

Chapter 16

In Summary

When it comes to finding the perfect titanium anode manufacturer, the key is to select one that not only offers a broad array of customized products but also possesses deep knowledge in various applications, ranging from chlor-alkali processes to water treatment. This ensures that each unique requirement is met with precision and expertise.

Hele Titanium stands at the forefront of the Mixed Metal Oxide (MMO) titanium anode industry, backed by more than ten years of exceptional experience. Our commitment is reflected in the superior quality of our materials, coatings, and product specifications, contributing to the success of numerous projects worldwide. Regardless of the scale of your project, our skilled team is prepared to meet your specific demands. Partner with Hele Titanium to discover the perfect solution tailored to your project’s needs, reinforcing our position as your reliable ally in achieving your goals.

Tailor Your Titanium Anode Solution Today

Advance your operations with Hele Titanium’s superior anodes. Our direct control over raw material production guarantees the highest quality at competitive prices. Customized to your specifications, our anodes deliver unmatched durability and efficiency. Trust in Hele Titanium for solutions that are precision-crafted to drive your success.

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